Seeking higher resolution and sensitivity for NMR of quadrupolar nuclei at ultrahigh magnetic fields.
نویسندگان
چکیده
We report the acquisition of solid-state NMR spectra of quadrupolar nuclei obtained at very high magnetic fields (25 and 40 T), thus improving spectral sensitivity and resolution. For an example compound, the MAS spectrum obtained at 40 T is nearly free from the second-order quadrupolar broadening and can be interpreted quantitatively in a very simple manner.
منابع مشابه
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 124 20 شماره
صفحات -
تاریخ انتشار 2002